Journal
HETEROCYCLES
Volume 84, Issue 1, Pages 527-535Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-11-S(P)16
Keywords
TPEN; [2+2+2] Cycloaddition; Soft Metal Ion; Ruthenium Catalyst; TPEN-NIPA Gel
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Funding
- Japan Society for the Promotion of Science (JSPS) [21655051]
- Grants-in-Aid for Scientific Research [21655051] Funding Source: KAKEN
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Hydrophobic TPEN (N,N,N',N'-tetrakispyridylmethyl-1,2-ethylene-diamine) derivatives are prepared by [2+2+2]cycloaddition of 1,omega-diyne and bromoacetonitrile leading to bromomethylpyridine and following reaction of 1,2-ethylenediamine. The obtained TPEN derivatives are employed for extraction of a soft metal ion such as cadmium(II).
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