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SYNTHETIC STUDIES ON NITROGEN-CONTAINING FUSED-HETEROCYCLIC COMPOUNDS BASED ON THERMAL ELECTROCYCLIC REACTIONS OF 6π-ELECTRON AND AZA 6π-ELECTRON SYSTEMS

Journal

HETEROCYCLES
Volume 83, Issue 6, Pages 1205-1239

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-10-691

Keywords

Electrocyclization; Allene Mediated Hexatriene; 1-Azahexatriene System; 2-Azahexatriene System; Microwave

Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. Fukuyama University

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Syntheses of carbazole alkaloids and indoles by an allene-mediated electrocyclic reaction of a 6 pi-electron system (II) through a tautomeric process, and syntheses of several fused pyridine ring systems including alkaloids by a thermal electrocyclic reaction of an aza 6 pi-electron system having an oxime or isocyanate (III) through either the elimination of a small molecule or a tautomeric process are described.

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