4.2 Article

SYNTHESIS OF HETARENOINDANONE BASED ON SELENIUM DIOXIDE-PROMOTED DIRECT INTRAMOLECULAR CYCLIZATION

Journal

HETEROCYCLES
Volume 83, Issue 10, Pages 2337-2342

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-11-12284

Keywords

Allylic Oxidation; Selenium Dioxide; Thiochromene; Intramolecular Friedel-Crafts Reaction; Hetarenoindanone

Funding

  1. Nara Institute of Science and Technology (NAIST)

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An alternative and simple method to prepare hetarenoindanone via intramolecular cyclization has been studied. This reaction represents the first example of an intramolecular Friedel-Crafts reaction-oxidation cascade promoted by selenium dioxide by way of Riley allylic oxidation.

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