Journal
HETEROCYCLES
Volume 80, Issue 2, Pages 697-724Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-09-SR(S)5
Keywords
Palladium; Carbonylation; Coupling Reaction; Boronic Acid; Nazarov Reaction
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A full account of our most recent studies on the chemistry of lactam-, lactone-, and thiolactone-derived vinyl triflates and phosphates is reported. In this review we focus on the use of these versatile electrophiles in Pd-catalyzed carbonylative reactions. They provide, through alkoxycarbonylation, aminocarbonylation and carbonylative Suzuki-Miyaura reactions, a straightforward and convenient access to useful intermediates for the synthesis of N-, O- and S-heterocyclic and natural compounds.
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