4.2 Article

THE SYNTHESIS OF SOME BENZIMIDAZOLIUM SALTS AND USE AS CARBENE PRECURSORS IN THE HECK AND SUZUKI REACTIONS

Journal

HETEROCYCLES
Volume 81, Issue 4, Pages 943-953

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-09-11896

Keywords

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Funding

  1. Technological and Scientific Research Council of Turkiye TUBITAK/CNRS, TUBITAK [107T419, TBAG-U/181 (106T716]
  2. Adiyaman University Research Fund [FEFBAP 2009-7, 2009-8]

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Novel 1-(2-diisopropylaminoethyl)-3-alkylbenzimidazolium salts as N-heterocyclic carbene precursors 2a-g were prepared by quarternazition of 1-(2-diisopropylaminoethyl)benzimidazoles in DMF with alkyl halides. The salts were characterized spectroscopically and in situ formed complexes from Pd(OAc)(2) and 2 have been tested as catalyst in homogenous Heck and Suzuki reactions.

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