4.2 Review

ENANTIOSELECTIVE RADICAL CYCLIZATION FOR THE SYNTHESIS OF CYCLIC COMPOUNDS

Journal

HETEROCYCLES
Volume 79, Issue -, Pages 229-242

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-08-SR(D)8

Keywords

Radical; Cyclization; Enantioselective Reaction; Lewis Acid; Organocatalyst

Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan
  2. Hyogo Science and Technology Association

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This review highlights the enantioselective radical cyclization reactions catalyzed by chiral Lewis acid as well as organocatalyst. The results of the radical cyclization controlled by chiral Al, Ti, Mg, Yb and Zn reagents, the oxidative cyclization using chiral amine, the chiral complexing agent-catalyzed reductive cyclization, transfer of chirality in radical cyclization, and so on are summarized.

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