Journal
HETEROCYCLES
Volume 77, Issue 1, Pages 157-161Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(F)6
Keywords
Cortistatin; Natural Product; Hypervalent Iodine; Oxidative Dearomatization; Cyclization
Categories
Funding
- National Institutes of Health [HL25848]
- Guthikonda family
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The feasibility of a hypervalent iodine-mediated oxidative dearomatization/cyclization to produce the oxabicyclo[3.2.1]octene of cortistatin A has been demonstrated through a model study. An interesting tandem cyclization via a Ritter intermediate has been observed when a slightly different substrate was used.
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