Journal
HETEROCYCLES
Volume 76, Issue 2, Pages 1261-1270Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(N)92
Keywords
Cyclopropene; Bond Cleavage; Cycloaddition; Rhodium; Cyclopentadiene
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
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In the presence of a catalytic amount of RhCl(PPh(3))(3), an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.
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