4.2 Article

RHODIUM-CATALYZED INTRAMOLECULAR CYCLOADDITION OF CYCLOPROPENE-YNES TRIGGERED BY CABON-CARBON BOND CLEAVAGE

Journal

HETEROCYCLES
Volume 76, Issue 2, Pages 1261-1270

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(N)92

Keywords

Cyclopropene; Bond Cleavage; Cycloaddition; Rhodium; Cyclopentadiene

Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan

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In the presence of a catalytic amount of RhCl(PPh(3))(3), an intramolecular cycloaddition of cyclopropene-yne proceeded along with carbon-carbon bond cleavage of cyclopropene ring to give various bicyclic cyclopentadiene derivatives in good to high yield.

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