Journal
HETEROATOM CHEMISTRY
Volume 19, Issue 6, Pages 644-648Publisher
WILEY-HINDAWI
DOI: 10.1002/hc.20490
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Funding
- the Ministry of Education, Science, Sports, Culture, and Technology, Japan [18850015]
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Bi(OTf)(3) effectively catalyzed the cyclization of amino-1,6-enynes, leading to bicyclic amine and cyclopentadienyl amino compounds. The selectivity of the products depends on the substitution pattern of the olefinic moiety. F-19 NMR trace experiment of the reaction and other results indicate a novel alkynophilicity of the bismuth species. (C) 2008 Wiley Periodicals, Inc.
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