Journal
HELVETICA CHIMICA ACTA
Volume 97, Issue 7, Pages 939-956Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201300339
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Funding
- CNRS
- Universite de Versailles Saint Quentin en Yvelines
- Continental Automotive Rambouillet
- Institut Universitaire de France
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An iridium(III) complex comprising three different cyclometalated phenylpyridine-based ligands was designed and synthesized. Interestingly, mixed-ligand complexes could be obtained by using a simple and straightforward procedure. A tris(heteroleptic) Ir-III complex was obtained as a mixture of stereoisomers that could not be separated. Photophysical properties of the tris(heteroleptic) complex was investigated by UV/VIS absorption and luminescence spectroscopy, and compared with those of the parent homoleptic complexes. Modelling by time-dependent density functional theory (TD-DFT) was also performed to elucidate the nature and the location of the excited state, and to support the experimental results.
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