Journal
HELVETICA CHIMICA ACTA
Volume 96, Issue 2, Pages 309-312Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201200166
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Funding
- programs for New Century Excellent Talents in University [NCET-09-0112]
- National Natural Science Foundation [31071701, 31171885]
- Hebei Province Science Fund for Distinguished Young Scholars [C2011201113]
- National High Technology Research and Development Program ('863' Program) [2011AA10A205]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1124]
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A new glycine derivative, podocarpiamide (1), a new indole alkaloid, 1-methoxy-1H-indol-3-ethanol (2), together with two known compounds, 1-methoxy-1H-indole-3-acetic acid (3) and methyl 1-methoxy-1H-indole-3-acetate (4), were isolated from the fermentation broth of the plant endophytic fungus Pestalotiopsis podocarpi. Their structures were elucidated by extensive spectroscopic analysis including 1D- and 2D-NMR (HSQC, HMBC, and COSY) and MS experiments. Compound 1 has an interesting unusual carbamic acid structure.
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