Journal
HELVETICA CHIMICA ACTA
Volume 96, Issue 3, Pages 499-504Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201200255
Keywords
Daphniphyllum macropodum; Alkaloids; Macrodumines AC
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Funding
- National Natural Science Foundation [81021062, 20902095]
- National Science and Technology Major Project 'Key New Drug Creation and Manufacturing Program' of the P. R. China [2011ZX09307-002-03]
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Three new alkaloids, macrodumines AC (13, resp.), along with ten known analogs, were isolated from the twigs and leaves of Daphniphyllum macropodum. Their structures were elucidated on the basis of spectroscopic methods. The 11-OH configuration of the known alkaloid hydroxydaphgraciline (4) was assigned as for the first time by comparing the NMR data with those of macrodumine C (3).
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