Journal
HELVETICA CHIMICA ACTA
Volume 93, Issue 6, Pages 1081-1085Publisher
WILEY-BLACKWELL
DOI: 10.1002/hlca.201000114
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Funding
- Trinity College, Dublin
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The reactions of secondary phosphanes with radical sources have been investigated. A stoichiometric dehydrocoupling of Ph(2)PH with 1,1'-azobis[cyclohexane-1-carbonitrile] (VAZO (R) 88) affords tetraphenyldiphosphane in good yields, whilst reduction of the nitrosyl function was observed upon using 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). Dialkylphosphane-borane adducts also undergo a dehydrocoupling reaction in the presence of VAZO (R) 88 to form R(4)P(2).
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