Journal
HELVETICA CHIMICA ACTA
Volume 92, Issue 11, Pages 2375-2386Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.200900173
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Funding
- DFG [SPP 1191]
- Fonds der Chemischen Industrie
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Two new Eu-based ionic liquid systems, [C(4)mim][DTSA]:[Eu(DTSA)(3)] and 2[C(4)mim] [DTSA]:[Eu(DTSA)3] were synthesized at 120`degrees under inert conditions from 1-butyl-1-methylimidazolium ditoluenesulfonylamide ([C(4)mim][DTSA]). The identity and purity of the synthesized compounds were confirmed by elemental analysis, IR, Raman, and H-1-NMR spectroscopy. As they solidify below 100 degrees as glasses they qualify as ionic liquids. Fluorescence measurements show that the materials exhibit a strong red luminescence of high color purity. Therefore, they have the potential to be used for optical applications such as in emission displays.
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